Seems like that charger makes an assumption that you will use the lipo storage mode coming from a lower voltage, not from a higher voltage - this is from pg 25 -
"With LiPo and LiFe batteries, the battery will be recharged and balanced to 3.85V/cell for LiPo and 3.3V/cell for LiFe. If the voltage is above 3.85V/cell for LiPo and 3.3V/cell for LiFe, the storage charge will stop as there is enough energy stored inside the batteries for a safe storage."
Haven't seen that before.....